Eco-Friendly Cork-Polyurethane Biocomposites for Enhanced Impact Performance: Experimental and Numerical Analysis.

Cork composites are byproducts from wine stopper production, resulting from the agglomeration of cork granules with a thermoset resin. The resulting compound is a versatile and durable material with numerous industrial applications. Due to its unique properties, such as low-density, high-strength, excellent energy absorption, and good thermal and acoustic insulators, cork composites find room for application in demanding industries such as automotive, construction, and aerospace. However, agglomerated cork typically has a polyurethane matrix derived from petrochemical sources. This study focuses on developing eco-friendly porous polyurethane biocomposites manufactured with the used cooking oil polyol modified with cork. Since cork and polyurethane foam are typically used for impact shock absorption, the manufactured samples were subjected to impact loading. The assessment of crashworthiness is performed through 100 J impact tests. A finite element numerical model was developed to simulate the compression of these new composites under impact, and the model validation was performed. The highest specific absorbed energy was obtained for petrochemical polyol composites with the 3% addition of natural or modified cork. The research conducted in this study showcased the feasibility of substituting certain petrochemical components used for the synthesis of the polyurethane matrix with ecological waste vegetable oil components.

Crashworthiness Characteristic of Dynamically Expanded Circular Tubes Made of Light Alloys: Experimental and Theoretical Investigation.

The paper presents the process of dynamic expansion of thin-walled pipes made of T6 temper 7075 aluminum alloy. The obtained results were related to the mass of tested elements, which allowed for calculating the specific energy absorption. The registered crushing force was in the range of 600-800 kN/kg. The obtained values were much greater than the crushing force of traditional crash boxes made of steel (80-120 kN/kg) or AZ31 magnesium alloy sheets (150 kN/kg). The analytical model for predicting crushing force depending on the thickness of the pipe wall was developed and proven to be correct by conducting real experiments and FEM simulation. The mathematical model for energy absorption named further as ETMEA (expanding tubes model for energy absorption) was developed based on calculated energy-deflection curves. It was proven that the energy absorption could be easily scaled. In cases where high energy absorption is needed, it can be easily achieved by increasing the thickness, while for lower energy absorption application, the thickness may be reduced and the goal may be achieved by selecting the appropriate length of the profile.

Development and Testing of Advanced Cork Composite Sandwiches for Energy-Absorbing Structures.

Cork is a sustainable material with remarkable properties. In addition to its main application as wine stoppers, it has also been employed as a sound and thermal insulator in facades, building roofs, aeronautical applications, and, more recently, in impact energy absorption systems. In its natural form, cork is mainly used in wine stopper manufacturing, but for other applications, cork compounds are usually employed, which makes it possible to manufacture complex geometries with nearly isotropic behavior. In this work, an attempt was made to merge the desirable properties of two different cork materials (agglomerated and expanded black) into cork composite sandwich structures. These structures were tested according to impact conditions typically experienced by energy-absorbing liners used in personal safety devices. Additionally, the performance dependency on the working temperature was analyzed. The sole black, expanded cork (EC159) and agglomerated cork (AC199A and AC216) were tested in 500 J impacts. It was found that black cork was characterized by superior thermal stability, while expanded cork allowed absorbing high energies. In the second stage, the composites consisting of both tested materials were tested in 100 J impact scenarios. The combination of two materials of different properties enabled reduction of the peak force exerted on a helmet user's head during the impact by about 10% compared to agglomerated specimens. Additionally, it was proved that there was no influence of the glue used to join different cork types.

Graphene-Enriched Agglomerated Cork Material and Its Behaviour under Quasi-Static and Dynamic Loading.

The use of cork for a variety of applications has been gaining significance due to environmental concerns and political agendas. Consequently, its range of applications is growing rapidly. In this work, aiming to improve its mechanical response for crashworthiness applications, cork agglomerates were enriched by small quantities of graphene oxide or graphene nanoplates in order to observe a resulting improvement of the mechanical behaviour during quasi-static and dynamic compressive loading cases. To produce homogenous cork agglomerates including graphene, the material was previously dispersed into granulated cork using stirrers to achieve a good distribution. Then, the typical procedure of compression and curing was carried out. Magnified images attest a good dispersion of graphene into the cork matrix. Mechanical testing was performed for a variety of graphene concentrations (0.1, 0.5 and 1.0 weight %), becoming clear that the beneficial effect of including graphene (either oxide or nanoplates) is related to a later densification stage while keeping the same stress plateau levels.